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Friedel-Crafts Alkylation of Aromatics with Alcohols and Transalkylation Reactions
Friedel-Crafts Alkylation of Aromatics with Alcohols and Transalkylation Reactions
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The Friedel-Crafts alkylation is a powerful substitution reaction to synthesize alkylphenols. Substitution by an alkyl group results from attack on the aromatic hydrocarbon by a cation (carbonium ion), a neutral fragment (free radical) or an anion (carbanion). The use of alcohol as alkylating agent for Friedel-Crafts reaction gives the benefit of a long stable life of the catalyst and ease of storage and transportation. The alkylphenols prepared from the alkylation of aromatics with alcohol has…
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  • ISBN-10: 1636480268
  • ISBN-13: 9781636480268
  • Format: 15.2 x 22.9 x 0.2 cm, minkšti viršeliai
  • Language: English
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Friedel-Crafts Alkylation of Aromatics with Alcohols and Transalkylation Reactions (e-book) (used book) | bookbook.eu

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The Friedel-Crafts alkylation is a powerful substitution reaction to synthesize alkylphenols. Substitution by an alkyl group results from attack on the aromatic hydrocarbon by a cation (carbonium ion), a neutral fragment (free radical) or an anion (carbanion). The use of alcohol as alkylating agent for Friedel-Crafts reaction gives the benefit of a long stable life of the catalyst and ease of storage and transportation. The alkylphenols prepared from the alkylation of aromatics with alcohol has industrial applications in the production of high-octane gasoline and synthetic rubbers, fibres, detergents, and plastics. The yield of desired alkylphenols is further enhanced by transalkylation of the side products, di-alkylphenols, with similar or dissimilar molecules. This review details the progress of alkylation and transalkylation of aromatics with alcohols over tailor-make zeolite molecular sieves and room temperature ionic liquids to get a high yield and selectivity for a particular reaction of interest.

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  • Author: Gul Afreen
  • Publisher:
  • ISBN-10: 1636480268
  • ISBN-13: 9781636480268
  • Format: 15.2 x 22.9 x 0.2 cm, minkšti viršeliai
  • Language: English English

The Friedel-Crafts alkylation is a powerful substitution reaction to synthesize alkylphenols. Substitution by an alkyl group results from attack on the aromatic hydrocarbon by a cation (carbonium ion), a neutral fragment (free radical) or an anion (carbanion). The use of alcohol as alkylating agent for Friedel-Crafts reaction gives the benefit of a long stable life of the catalyst and ease of storage and transportation. The alkylphenols prepared from the alkylation of aromatics with alcohol has industrial applications in the production of high-octane gasoline and synthetic rubbers, fibres, detergents, and plastics. The yield of desired alkylphenols is further enhanced by transalkylation of the side products, di-alkylphenols, with similar or dissimilar molecules. This review details the progress of alkylation and transalkylation of aromatics with alcohols over tailor-make zeolite molecular sieves and room temperature ionic liquids to get a high yield and selectivity for a particular reaction of interest.

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